Product ID:MAGNOBOND 41-4
MSDS Date:05/07/1987
FSC:8040
NIIN:00F017738
MSDS Number: BKWJH

MAGNOLIA PLASTIC INC

5547 PEACHTREE INDUSTRIAL BOULEVARD
CHAMBLEE, GA 30341

Emergency Phone: (404) 451-2777

Info Phone: (404) 451-2777

Cage: 22121

MAGNOLIA PLASTICS INC

CHAMBLEE, GA 30341-2234 US

Telephone: (770) 451-2777/(800) 457-4280

Cage: 22121

4,4'-METHYLENE DIANILINE (SARA III)

CAS: 101-77-9

RTECS: BY5425000

Fraction By Weight: 35%

ACGIH TLV: S; 0.1 PPM; A2; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE TRIAMINE

CAS: 14-40-0

RTECS: IE1225000

Fraction By Weight: 10-15%

ACGIH TLV: 1 PPM (SKIN)

ALKYLENEAMINE

Fraction By Weight: 5-15%

Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INGESTION: DIGESTIVE TRACT IRRIATION.
INHALATION: RESPIRATORY TRACT IRRITATION, ABNORMAL LIVER & KIDNEY
EFFECTS. SKIN: IRRITATION, SENSITIZATION, ABSORPTION, ALLERGIC
REACTION, RASH, & STAIN. EYES: IR RITATION & BURNS.
Explanation of Carcinogenicity:4,4-METHYLENE DIANILINE (MDA) IS A
SUSPECTED A2 HUMAN CARCINOGEN.
Effects of Overexposure:INGESTION: DIGESTIVE TRACT IRRITATION.
INHALATION: RESPIRATORY TRACT IRRITATION, ABNORMAL LIVER & KIDNEY
EFFECTS. SKIN: IRRITATION, SENSITIZATION, ABSORPTION, ALLERGIC
REACTION, RASH, & STAIN. EYES: I RRITATION & BURNS.

First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS.
INGESTION: INDUCE VOMITING BY GIVING 2 GLASSES OF WATER.
INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:PMCC
Flash Point:>200F
Extinguishing Media:WATER SPRAY, FOAM, CO2, OR DRY CHEMICAL.
Fire Fighting Procedures:IN CONFINED AREAS, WEAR A FULL FIRE FIGHTING
EQUIPMENT & NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL
FIRE-EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:CORROSIVE MATERIAL.

Spill Release Procedures:WIPE W/A CLOTH OR COLLECT ON ABSORBENT
MATERIAL. LARGE SPILLS: DIKE & CONTAIN. PUMP OR SHOVEL INTO SALVAGE
VESSELS.

Handling and Storage Precautions:STORE IN A COOL, DRY AREA IN TIGHTLY
CLOSED CONTAINERS. USE W/ADEQUATE VENTILATION. FOR INDUSTRIAL USE
ONLY.
Other Precautions:AVOID CONTACT W/SKIN, EYES, BREATHING SMOKE, OR
CONTACT W/LIQUID & VAPORS. AVOID LARGE MIXTURES IN BULK, CURING
PROCESS IS EXOTHERMIC.

Respiratory Protection:TO KEEP FOR ORGANIC VAPORS.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): RECOMMENDED
Protective Gloves:IMPERVIOUS RUBBER
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING, BOOTS, EYE-WASH STATION
& SAFETY SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. USE GOOD HYGIENE PRACTICES.
Supplemental Safety and Health
IF CURED PRODUCT IS MACHINED, AIRBORNE FIBEROUS DUST MAY BE PRESENT.

Boiling Pt:B.P. Text:>225F
Vapor Pres:0
Vapor Density:>1
Spec Gravity:1.78
Evaporation Rate & Reference:(BU AC =1): <1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BROWN LIQUID
Percent Volatiles by Volume:0%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, & BASES.
Stability Condition to Avoid:ELEVATED TEMPERATURES
Hazardous Decomposition Products:CO, CO2, & NITROGEN.

Waste Disposal Methods:CURE, THEN BURY OR INCINERATE. REMOVE SALVAGE
VESSELS TO A WASTE DISPOSAL SITE IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. CORROSIVE MATERIAL UN1760.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.